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Acid-Catalyzed Amine−Borane Reduction of Nitrite

✍ Scribed by Bell, Kevin E.; Kelly, Henry C.

Book ID
121467649
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
123 KB
Volume
35
Category
Article
ISSN
0020-1669

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Palladium catalyzed activation of borane
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Hydrolytically stable borane-amines can be activated in situ through palladium catalysis and perform reductions not possible otherwise. Hence, borane-trimethylamine is an efficient hydrogen-transfer reagent for the open vessel reduction of nitroaryls to anilines. Likewise, the palladium catalyzed me