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Hydrolysis of trimethylamine borane in the presence of liquid and solid (polymeric) acids

โœ Scribed by Dmitri Muraviev; Abraham Warshawsky


Book ID
108046785
Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
593 KB
Volume
31
Category
Article
ISSN
1381-5148

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Hydrolysis of trimethylamine borane in t
โœ Dmitri Muraviev; Abraham Warshawsky ๐Ÿ“‚ Article ๐Ÿ“… 1996 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 592 KB

The mechanism of trimethylamine borane (TMAB) hydrolysis in the presence of sulfonate cation exchanger in H+form, H2S03 and trimethylamine deuterosulfate has been established. The hydrolytic reaction is of the first order in TMAB when carried out in the presence of polymeric acid. The rate of TMAB h