Mixtures consisting of five equivalents each of borane.methyl sulfide and boron trifluoride etherate per equivalent of acetal or five equivalents of various amine-borane complexes and 10 equivalents of boron trifluoride etherate readily accomplished reductive cleavage of the glycosidic linkages of s
Amine Borane Reductions. The Stereochemistry of the Reduction of 4-t-Butylcyclohexanone with Trimethylamine Borane in the Presence and Absence of Boron Fluoride
โ Scribed by Jones, W. M.
- Book ID
- 127156489
- Publisher
- American Chemical Society
- Year
- 1960
- Tongue
- English
- Weight
- 667 KB
- Volume
- 82
- Category
- Article
- ISSN
- 0002-7863
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๐ SIMILAR VOLUMES
Ammonia borane and primary amine boranes are highly chemoselective reducing agents for aldehydes and ketones. There has been much recent interest in the development of chemoselective1s2 reducing agents capable of distinguishing aldehyde and ketone functionality in a predictable manner. 'a-si While a
Primary and secondary amine boranes have been shown to be mild, efficient, and stereoselective reducing agents for aldehydes and ketones in protic or non-protic solvents with reactivity patterns different than diborane or sodium borohydride. During the course of our studies on new stereo-and them,-s