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The synthetic utility of amine borane reagents in the reduction of aldehydes and ketones

✍ Scribed by G.C. Andrews; T.C. Crawford

Publisher: Elsevier Science
Year: 1980
Tongue: French
Weight: 223 KB
Volume: 21
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)71448-1

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✦ Synopsis

Primary and secondary amine boranes have been shown to be mild, efficient, and stereoselective reducing agents for aldehydes and ketones in protic or non-protic solvents with reactivity patterns different than diborane or sodium borohydride. During the course of our studies on new stereo-and them,-selective reducing agents we have found that the reactivity and stereoselectivity of amine borane reagents is highly dependent on the nature of the amine used in the amine borane complex. In fact, contrary to much of the

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