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Transfer Reactions Involving Boron. VIII. The Stereochemistry and Mechanism of the Reduction of Epoxides with Borane-d 3 -Tetrahydrofuran 1,2

✍ Scribed by Pasto, Daniel J.; Cumbo, Charles C.; Hickman, James


Book ID
127220542
Publisher
American Chemical Society
Year
1966
Tongue
English
Weight
887 KB
Volume
88
Category
Article
ISSN
0002-7863

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Reactions of the title compounds with sodium methoxide and sodium borodeuteride were found to proceed mainly via the SK2' mechanism; nucleophiles selectively attacked the anomeric carbon atom from the same side of the leaving acetoxyl group at C-3.