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Amidine catalysed O- to C-carboxyl transfer of heterocyclic carbonate derivatives

✍ Scribed by Joannesse, Caroline; Simal, Carmen; Concellón, Carmen; Thomson, Jennifer E.; Campbell, Craig D.; Slawin, Alexandra M. Z.; Smith, Andrew D.

Book ID: 118740849
Publisher: Royal Society of Chemistry
Year: 2008
Tongue: English
Weight: 263 KB
Volume: 6
Category: Article
ISSN: 1477-0520
DOI: 10.1039/B805850D

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## Abstract The structural motif within a series of tetrahydropyrimidine‐based isothioureas necessary for generating high asymmetric induction in the asymmetric Steglich rearrangement of oxazolyl carbonates is fully explored, with crossover and dynamic ^19^F NMR experiments used to develop a mechan

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