Isothiourea-Mediated Asymmetric O- to C-
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Caroline Joannesse; Craig P. Johnston; Louis C. Morrill; Philip A. Woods; Madele
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Article
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2012
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John Wiley and Sons
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English
⚖ 773 KB
## Abstract The structural motif within a series of tetrahydropyrimidine‐based isothioureas necessary for generating high asymmetric induction in the asymmetric Steglich rearrangement of oxazolyl carbonates is fully explored, with crossover and dynamic ^19^F NMR experiments used to develop a mechan