Aluminum–Magnesium Complexes with Linearly Bridging Carbon Dioxide
✍ Scribed by Chung-Cheng Chang; Min-Chun Liao; Tsu-Hsin Chang; Shie-Ming Peng; Gene-Hsiang Lee
- Book ID
- 101561150
- Publisher
- John Wiley and Sons
- Year
- 2005
- Tongue
- English
- Weight
- 122 KB
- Volume
- 44
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
Transition-metal complexes, CoHMD 2 + (HMD = 5, 7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene) and Ru(bpy) 2 (CO)X n + (bpy= 2,2%-bipyridine, X =CO, Cl, H, etc.), mediate electron transfer in the photochemical reduction of CO 2 . The thermodynamics and kinetics of CO 2 binding t
The reaction of oxalic amidines R 1 -N=C(NHR 2 )-C(NHR 2 )= N-R 1 with CH 3 MgX followed by uptake of CO 2 results in the formation of the trimeric carbamato complexes [R 1 -N= C(NR 2 -COO)-C(NR 2 COO)=N-R 1 ] 3 Mg 3 (THF) 6 (2a: R 1 = R 2 = Ph; 2b: R 1 = R 2 = p-tolyl) as the thermodynamically stab
The structures and the related vibrational spectra of the AICO2 complexes are investigated using a local spin density functional method. The calculations indicate in agreement with a recent spectroscopic study on this system, the existence of two isomers with almost the same energy ( < 2 kcal/mol).