β Scribed by Etsuko Fujita
No coin nor oath required. For personal study only.
Transition-metal complexes, CoHMD 2 + (HMD = 5, 7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene) and Ru(bpy) 2 (CO)X n + (bpy= 2,2%-bipyridine, X =CO, Cl, H, etc.), mediate electron transfer in the photochemical reduction of CO 2 . The thermodynamics and kinetics of CO 2 binding to CoHMD + , and spectroscopic characterization of the CO 2 adducts of CoHMD + and [Ru I (bpy)(bpy -)(CO)] are described.
π SIMILAR VOLUMES
The properties and potential applications of carbon freshly made from high purity CO gas (99.91%) were 2 added to ensure the CO being in a supercritical state nanotubes (CNTs) such as superconductors [1], single-2 (critical point, 31 8C, 73 atm) at high temperatures. A molecular transistors [2,3] an