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Alternating Ethene/Propene Copolymerization with a Metallocene Catalyst

✍ Scribed by Margarete K. Leclerc; Robert M. Waymouth


Publisher
John Wiley and Sons
Year
1998
Tongue
English
Weight
95 KB
Volume
37
Category
Article
ISSN
0044-8249

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Ethene was copolymerized in liquid propene with a high activity heterogeneous MgCI2/TiCI 4triethytaluminium catalyst and with homogeneous VOCl3-diethylaluminiumchloride and Cp2ZrCl2-methylaluminoxane catalysts to study the effect of the catalyst system on the properties of the products. The titanium

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## Abstract Summary: Propene‐ethene copolymers with low to moderate amounts of ethene were synthesised with two __C__~s~‐symmetric metallocene complexes, [(__p__‐CH~3~OPh)~2~C(2,7‐di‐^__t__^BuFlu)(Cp)]ZrCl~2~ (I) and [(__p__‐CH~3~OPh)~2~C(2,7‐di‐^__t__^BuFlu)(Cp)]HfCl~2~ (Ia). Methylalumoxane (MAO)