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Copolymerization of propene with phenylnorbornene using ansa-bridged metallocene catalysts

✍ Scribed by Erkki Aitola; Timo Repo; Christer Bergström; Markku Leskelä


Publisher
John Wiley and Sons
Year
2002
Tongue
English
Weight
178 KB
Volume
84
Category
Article
ISSN
0021-8995

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Copolymerization of ethylene with a symmetrical diene, namely, 2,5-norbornadiene was studied using a homogeneous metallocene/MAO catalyst system. Copolymerizations were found to occur exclusively through one of the two equally reactive endocyclic double bonds with Cp 2 ZrCl 2 , (buCp) 2 ZrCl 2 and E