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Copolymerization of ethene and propene in liquid propene with MgCl2/TiCl4, VOCl3 and Cp2ZrCl2 catalyst systems—A comparison of products

✍ Scribed by Jari Koivumäki; Jukka V. Seppälä

Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
319 KB
Volume
30
Category
Article
ISSN
0014-3057

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✦ Synopsis

Ethene was copolymerized in liquid propene with a high activity heterogeneous MgCI2/TiCI 4triethytaluminium catalyst and with homogeneous VOCl3-diethylaluminiumchloride and Cp2ZrCl2-methylaluminoxane catalysts to study the effect of the catalyst system on the properties of the products. The titanium catalyst gave crystallizable ethene blockies at high ethene contents and the zirconium catalyst gave the most random distribution of the monomers. The differences in the properties of the polymers were not so great as expected.

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