Allylbiscyclopentadienyltitanium(III) and -vanadium(III)
β Scribed by Drs. Hendrik A. Martin; Prof. Dr. F. Jellinek
- Publisher
- John Wiley and Sons
- Year
- 1964
- Tongue
- English
- Weight
- 133 KB
- Volume
- 3
- Category
- Article
- ISSN
- 0044-8249
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π SIMILAR VOLUMES
The synthesis and structural and magnetic characterisation of three new vanadium(III) phosphonate cage complexes are reported. The exchange interactions vary from Γ30 to +30 cm Γ1 and appear to be dependent on the superexchange path between vanadium centers.
## C 32.23, H 5.58, P 8.13, Cl 2.33, V 21.73; found: C 33.71, H 6.08, P 7.74, Cl 2.63, V 20.15. Magnetic susceptibility (5 kG and 1.0 T applied fields) measurements were performed on polycrystalline samples on a Quantum Design MPMS SQUID magnetometer. Data are corrected for diamagnetic contributio