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Synthesis of Molecular Vanadium(III) Phosphonates

✍ Scribed by Sumit Khanra; Marc Kloth; Hassanatu Mansaray; Christopher A. Muryn; Floriana Tuna; E. Carolina Sañudo; Madeleine Helliwell; Eric J. L. McInnes; Richard E. P. Winpenny

Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
173 KB
Volume
46
Category
Article
ISSN
0044-8249

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✦ Synopsis

C 32.23, H 5.58, P 8.13, Cl 2.33, V 21.73; found: C 33.71, H 6.08, P 7.74, Cl 2.63, V 20.15.

Magnetic susceptibility (5 kG and 1.0 T applied fields) measurements were performed on polycrystalline samples on a Quantum Design MPMS SQUID magnetometer. Data are corrected for diamagnetic contributions according to the Pascal constants.

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Vanadium(III) phosphonate cage complexes
Vanadium(III) phosphonate cage complexes
✍ Sumit Khanra; Luke Batchelor; Madeleine Helliwell; Floriana Tuna; Eric. J.L. McI 📂 Article 📅 2008 🏛 Elsevier Science 🌐 English ⚖ 312 KB

The synthesis and structural and magnetic characterisation of three new vanadium(III) phosphonate cage complexes are reported. The exchange interactions vary from À30 to +30 cm À1 and appear to be dependent on the superexchange path between vanadium centers.