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Vanadium(III) phosphonate cage complexes

✍ Scribed by Sumit Khanra; Luke Batchelor; Madeleine Helliwell; Floriana Tuna; Eric. J.L. McInnes; Richard E.P. Winpenny

Publisher: Elsevier Science
Year: 2008
Tongue: English
Weight: 312 KB
Volume: 890
Category: Article
ISSN: 0022-2860
DOI: 10.1016/j.molstruc.2008.03.026

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✦ Synopsis

The synthesis and structural and magnetic characterisation of three new vanadium(III) phosphonate cage complexes are reported. The exchange interactions vary from À30 to +30 cm À1 and appear to be dependent on the superexchange path between vanadium centers.

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