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Alkyne-Functionalized Zirconocene Complexes: Synthesis, Structures, and Reactivities

✍ Scribed by Li, Minxiong; Song, Haibin; Xu, Shansheng; Wang, Baiquan

Book ID
121331702
Publisher
American Chemical Society
Year
2010
Tongue
English
Weight
950 KB
Volume
29
Category
Article
ISSN
0276-7333

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Isomerization of olefins by titanocene a
Isomerization of olefins by titanocene and zirconocene alkyne complexes
✍ A. Ohff; V.V. Burlakov; U. Rosenthal πŸ“‚ Article πŸ“… 1996 πŸ› Elsevier Science 🌐 English βš– 690 KB

An efficient isomerization of aliphatic and cyclic olelins is achieved by using well-defined metallocene alkyne complexes as catalysts. Titanocene complexes isomerize I-alkenes to internal alkenes under mild conditions. The titanium complex was recovered quantitatively. Cyclic olcfins, e.g. cyclohex