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Alkyne-niobium(I) complexes with functionalized alkynes: synthesis, structure and reactivity

✍ Scribed by Dieter Rodewald; Carola Schulzke; Dieter Rehder


Book ID
103232221
Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
543 KB
Volume
498
Category
Article
ISSN
0022-328X

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The coordination behaviour of 2,6-disilyl-substituted characterized. The formation of 6 results from a [4 + 2] cycloaddition between one alkynyl group of each phosphinine phosphinines towards gold(I) has been examined. The reaction of the bis(trimethylsilyl)phosphinine 1 with [AuCl(SMe 2 )] gives wi