๐”– Bobbio Scriptorium
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The synthesis, reactions and molecular structure of zirconocene-alkyne complexes

โœ Scribed by Buchwald, Stephen L.; Watson, Brett T.; Huffman, John C.


Book ID
121265841
Publisher
American Chemical Society
Year
1987
Tongue
English
Weight
337 KB
Volume
109
Category
Article
ISSN
0002-7863

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Zirconocene I Titanocene I Benzoxazoles I Thiazoles J Benzisoxazoles Zirconocene alkyne complexes Cp2Zr(L)(Me3SiC2R) (L = Py, THF; R = %Mes, tBu) react with heterocyclic compounds like benzoxazole and related thiazoles t o yield ring-expanded adducts Cp,h-C(SiMe,) =C(R) -CH=No -C 6 h -k ( 1-3) and C