Alkylation of amines using trivalent bismuth derivatives
โ Scribed by Derek H.R. Barton; Nubar Ozbalik; Manian Ramesh
- Book ID
- 104217906
- Publisher
- Elsevier Science
- Year
- 1988
- Tongue
- French
- Weight
- 194 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0040-4039
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โฆ Synopsis
Mixed alkylaryl Bi*" derivatives have been prepared by both anionic and free radical methods. The thermal stability of these compounds permits them to be used in the presence of cupric acetate for the alkylation of amines. Trialkylbismuth compounds can also be used in the same way.
๐ SIMILAR VOLUMES
The significant advances in achiral catalysis using N-heterocyclic carbene (NHC) metal complexes have prompted intense investigation of chiral NHC derivatives for use in asymmetric catalysis in recent years. Discovery of new chiral NHC catalysts is supported by the development of synthetic routes to