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Alkylated Adrenal Hormones. The Synthesis of 6α-Methyl Cortical Steroids

✍ Scribed by Fried, John H.; Arth, Glen E.; Sarett, Lewis H.

Book ID
120880571
Publisher
American Chemical Society
Year
1959
Tongue
English
Weight
708 KB
Volume
81
Category
Article
ISSN
0002-7863

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✍ A. Bowers; E. Denot; M.Blanca Sanchez; H.L. Ringold 📂 Article 📅 1959 🏛 Elsevier Science 🌐 French ⚖ 73 KB

## Incubation of 6u-fluoro-Reichstein's Compound 3'" (I) and its A'-analog (IV) with bovine adrenals followed by acetylation led to 6c4uorohydrocortisone acetate (II) and 6a-fluoroprednisolone acetate (III) respectively. Selenium dioxide oxidation of II also afforded III. Chromium trioxide oxidati