✦ LIBER ✦

Alkyl radical disproportionation

✍ Scribed by Thommarson, R. L.

Book ID: 120528136
Publisher: American Chemical Society
Year: 1970
Tongue: English
Weight: 484 KB
Volume: 74
Category: Article
ISSN: 0022-3654
DOI: 10.1021/j100699a046

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Disproportionation of Halogenated Alkyl

Disproportionation of Halogenated Alkyl Radicals

✍ MAJER, J. R.; PHILLIPS, D. 📂 Article 📅 1964 🏛 Nature Publishing Group 🌐 English ⚖ 319 KB

The disproportionation and combination o

The disproportionation and combination of alkyl radicals

✍ R. S. Konar 📂 Article 📅 1970 🏛 John Wiley and Sons 🌐 English ⚖ 159 KB

Several attempts have been made to correlate the disproportionation and the combination rate constant ratio, k,/k,, of the alkyl radicals with the entropy change of the processes [ 1-31. Bradley [I] made a specific suggestion that the k,/k, ratio is a function of the entropy change of the processes

Disproportionation-combination ratios of

Disproportionation-combination ratios of large branched alkyl radicals

✍ J. H. Georgakakos; B. S. Rabinovitch; C. W. Larson 📂 Article 📅 1971 🏛 John Wiley and Sons 🌐 English ⚖ 790 KB

The disproportionation-combination reactions of radicals 4,4-dimethylpentyl-2 and 2,4-dimethylpentyl-2, produced by collisional stabilization of the respective chemically activated species, have been studied at 298"K, with and without getter radicals. Use of getters t-C4H9 and CzHs with 4,4-dimethyl

Disproportionation reactions between alk

Disproportionation reactions between alkyl and fluoroalkyl radicals. IV. Pentafluoroethyl and ethyl radicals

✍ G. O. Pritchard; V. H. Kennedy; G. M. Heldoorn; M. L. Piasecki; K. A. Johnson; D 📂 Article 📅 1987 🏛 John Wiley and Sons 🌐 English ⚖ 552 KB

A new determination of the disproportionation/cornbination ratio for C2Fs and CZH, radicals gives a value of A(C2F,, C2H,) = 0.24 5 0.02, independent of temperature. The cross-combination ratio for the two radicals was found to increase with temperature and the significance of this is discussed in e

Stereoselective radical-radical dispropo

Stereoselective radical-radical disproportionation

✍ Ned A. Porter; Ian J. Rosenstein 📂 Article 📅 1993 🏛 Elsevier Science 🌐 French ⚖ 280 KB

Disproportionation reactions between alk

Disproportionation reactions between alkyl and fluoroalkyl radicals. VI. Difluoromethyl and n-propyl radicals

✍ G. O. Pritchard; S. H. Abbas; M. L. Piasecki; M. A. Meleason 📂 Article 📅 1991 🏛 John Wiley and Sons 🌐 English ⚖ 239 KB

Cross-disproportionation to combination ratios for CF2H and n-C3H7 radicals have been determined (the hydrogen acceptor radical is given first) to be A(n-C3H7,CF2H) = 0.30 2 0.01 and A(CF2H, n-C3H7) = 0.057 ? 0.006.