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Alkyl interchange in the mixture of triethyl aluminum and diethylaluminum chloride

✍ Scribed by Koichi Hatada; Heimei Yuki

Publisher
Elsevier Science
Year
1967
Tongue
French
Weight
206 KB
Volume
8
Category
Article
ISSN
0040-4039

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πŸ“œ SIMILAR VOLUMES

Exchange of alkylgroups in triethyl alum
Exchange of alkylgroups in triethyl aluminium, diethyl aluminium chloride and a mixture of these substances, and in a mixture of methyl aluminium dichloride and dimethyl aluminium chloride
✍ J. Smidt; M. P. Groenewege; H. de Vries πŸ“‚ Article πŸ“… 2010 πŸ› Elsevier Science 🌐 English βš– 229 KB

## Abstract Proton magnetic resonance has shown that there is exchange between the outer‐ and the bridge‐alkylgroups in dimeric triethyl aluminium at room temperature. At lower temperatures the rate of exchange diminishes, and at βˆ’60Β° exchange is hardly noticeable. In diethyl aluminium chloride no