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Control of the alkylation of ketone enolates with tributyl tin chloride and triethyl aluminum

✍ Scribed by P.A. Tardella


Publisher
Elsevier Science
Year
1969
Tongue
French
Weight
147 KB
Volume
10
Category
Article
ISSN
0040-4039

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One-step synthesis of Ξ±,Ξ²-unsaturated ke
✍ Jiro Tsuji; Ichiro Minami; Isao Shimizu πŸ“‚ Article πŸ“… 1983 πŸ› Elsevier Science 🌐 French βš– 115 KB

Enol acetates derived from saturated ketones are converted to a,&unsaturated ketones by heating with ally1 methyl carbonate in MeCN by bimetallic catalysis of palladiumphosphine complex and tin methoxide. Conversion of saturated ketones to corresponding a,&unsaturated ketones is an important synthet