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Alkene epoxidation catalysed by binuclear manganese complexes

✍ Scribed by Maria Louloudi; Chrisavgi Kolokytha; Nick Hadjiliadis


Book ID
104421723
Publisher
Elsevier Science
Year
2002
Tongue
English
Weight
57 KB
Volume
180
Category
Article
ISSN
1381-1169

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Alkane hydroxylation reactions catalysed
✍ David Tetard; Jean-Baptiste Verlhac πŸ“‚ Article πŸ“… 1996 πŸ› Elsevier Science 🌐 English βš– 773 KB

## Binuclear manganese(III/IV) or iron(III/III) complexes efficiently functionalize cyclohexane using hydroperoxides or peracids as oxidants. A mechanistic study clearly demonstrate the role of dioxygen gas in these hydroxylation reactions. Moreover, it was demonstrated that the cleavage of the pe