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Sodium Periodate Epoxidation of Alkenes Catalysed by Manganese Porphyrins

✍ Scribed by Mohajer, Daryoush; Tayebee, Reza; Goudarziafshar, Hameed


Book ID
126278293
Publisher
Science Reviews 2000 Ltd
Year
1999
Tongue
English
Weight
98 KB
Volume
2
Category
Article
ISSN
0308-2342

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A series of Mn III porphyrins progressively halogenated in the electrophilic pathway of addition and a stereospecific pathway of oxygen insertion, the former being disfavoured Ξ²-pyrrolic positions was employed to catalyse the epoxidation of cis-stilbene by iodosylbenzene, and to study by electron-wi