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Alkane hydroxylation reactions catalysed by binuclear manganese and iron complexes

✍ Scribed by David Tetard; Jean-Baptiste Verlhac

Publisher: Elsevier Science
Year: 1996
Tongue: English
Weight: 773 KB
Volume: 113
Category: Article
ISSN: 1381-1169
DOI: 10.1016/s1381-1169(97)80001-5

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✦ Synopsis

Binuclear manganese(III/IV)

or iron(III/III) complexes efficiently functionalize cyclohexane using hydroperoxides or peracids as oxidants. A mechanistic study clearly demonstrate the role of dioxygen gas in these hydroxylation reactions. Moreover, it was demonstrated that the cleavage of the peroxy bond occurred mainly by homolysis.

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