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Alkane oxidation with a new (μ-oxo)diiron(III) complex

✍ Scribed by Miguel A. Pérez; Manuel L. Morato

Book ID
103570359
Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
52 KB
Volume
59
Category
Article
ISSN
0162-0134

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✍ Ritam Mukherjee; Basab Bijayi Dhar; Rupendranath Banerjee 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 114 KB

## Abstract The complex ion [Fe^III^~2~(μ‐O)(phen)~4~(H~2~O)~2~]^4+^ (1) (phen = 1,10‐phenanthroline) and its hydrolytic derivatives [Fe^III^~2~(μ‐O)(phen)~4~(H~2~O)(OH)]^3+^ (1a) and [Fe^III^~2~(μ‐O)(phen)~4~‐ (OH)~2~]^2+^ (2a) coexist in rapid equilibria in the range pH 4.23–5.35 in the presence