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Alignment effects in the multiple photon ionisation of nitric oxide

✍ Scribed by J.P. Booth; S.L. Bragg; G. Hancock

Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
534 KB
Volume
113
Category
Article
ISSN
0009-2614

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✦ Synopsis

multiple photon ronimtion of NO(Xzn$ via the A 'z+ stale BL wavelengths near 226 nm gives 1011 signals which depend upon the value of Iti in the A-X transition, with P, R branch eacllation bcmg cnhdnced over Q branch acltation.

The results are rnterpretcd in terms of iorusation of aligned NO A 'E+ molecules, and Imply that the electron departs primarily as a pa wave. Implicatrons for the measurements of ground state NO populdtlons via two-step ionisation arc discussed.

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