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Correlation effects in the nitrogen 1s photoelectron spectrum of nitric oxide

✍ Scribed by T. Darko; I.H. Hillier; J. Kendrick

Publisher
Elsevier Science
Year
1977
Tongue
English
Weight
266 KB
Volume
45
Category
Article
ISSN
0009-2614

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✦ Synopsis

of tic anomalous intensity ratio of the two peaks arking from nitrogen 1s ionizatΓ­on of nitric oxide is presented. It is found that correlation effccts in both the ground state of NO, and the Γ­onic states 13il, ' fl) of NO+ contriiutc to deviations of this intcnsity ratio from the "frazen orbital" value of 3 to the experimental value of 3.43.iMC SCF calculations arc descriied which result Γ­n an excellent prediction of this intensity ratio. The satelhte praks associated with corc ionization from NO are briefly discusscd.

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