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Aldol-type reactions between trimethylsilyl enol ethers and acetals with the aid of rhodium complex

✍ Scribed by Susumu Sato; Isamu Matsuda; Yusuke Izumi

Publisher: Elsevier Science
Year: 1987
Tongue: French
Weight: 229 KB
Volume: 28
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)96938-7

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✦ Synopsis

Aldol-type reactions of trimethylsilyl enol ethers with acetals, ketals, and orthoesters are successfully performed with the aid of a catalytic amount of rhodium complex, Rh4(C0)12 or [Rh(COD)(DPPB)]+ClO,-, under neutral conditions.

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