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The first example of aldol reactions between trimethylsilyl enol ethers and aldehydes by the aid of rhodium complex

✍ Scribed by Susumu Sato; Isamu Matsuda; Yusuke Izumi

Publisher
Elsevier Science
Year
1986
Tongue
French
Weight
219 KB
Volume
27
Category
Article
ISSN
0040-4039

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✦ Synopsis

Crossed aldol reaction of trimethylsilyl enol ether with aldehyde is successfully performed with the aid of catalytic amount of rhodium complex, [(COD)Rh(DPPB)]+X-(X = PF6 and C104) or Rh4(C0)12, under neutral conditions.

πŸ“œ SIMILAR VOLUMES

Aldol-type reactions between trimethylsi
Aldol-type reactions between trimethylsilyl enol ethers and acetals with the aid of rhodium complex
✍ Susumu Sato; Isamu Matsuda; Yusuke Izumi πŸ“‚ Article πŸ“… 1987 πŸ› Elsevier Science 🌐 French βš– 229 KB

Aldol-type reactions of trimethylsilyl enol ethers with acetals, ketals, and orthoesters are successfully performed with the aid of a catalytic amount of rhodium complex, Rh4(C0)12 or [Rh(COD)(DPPB)]+ClO,-, under neutral conditions.