✦ LIBER ✦

Direct enantioselective synthesis of syn-1,3-diols by the reaction of aldehydes with enol silyl ethers in the presence of a chiral borane complex. Successive asymmetric aldol reaction and asymmetric reduction with one promoter

✍ Scribed by Yuichi Kaneko; Takao Matsuo; Syun-ichi Kiyooka

Publisher: Elsevier Science
Year: 1994
Tongue: French
Weight: 282 KB
Volume: 35
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)73125-x

No coin nor oath required. For personal study only.

✦ Synopsis

A stoicbiometric Itmomtofthccbiral~1turntdouttos

tlaxssivcly promote the aqmmehic aldol rcactioa of al&hy&s with cd silyl ethers and the rdowitlg asymmettic leductioa in om pot to affcrd syI&l3diols willlbighetity.

📜 SIMILAR VOLUMES

Diastereo- and Enantioselective Direct C

Diastereo- and Enantioselective Direct Catalytic Aldol Reaction of 2-Hydroxyacetophenones with Aldehydes Promoted by a Heteropolymetallic Complex: Catalytic Asymmetric Synthesis of anti-1,2-Diols.

✍ Naoki Yoshikawa; Takeyuki Suzuki; Masakatsu Shibasaki 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 38 KB 👁 2 views

ChemInform Abstract: A Divergent Synthes

ChemInform Abstract: A Divergent Synthesis of Essentially Enantiopure syn- and anti-Propionate Aldol Adducts Based on the Chiral 1,3,2-Oxazaborolidin-5-one-Promoted Asymmetric Aldol Reaction Followed by Diastereoselective Radical Reduction.

✍ Syun-ichi Kiyooka; Kazi Abuds Shahid 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 38 KB 👁 2 views