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Aldol-cyclization reaction sequence for the synthesis of tetrahydrofurans

✍ Scribed by Michael A. Calter; Priyantha M. Sugathapala; Cheng Zhu

Book ID: 104257128
Publisher: Elsevier Science
Year: 1997
Tongue: French
Weight: 194 KB
Volume: 38
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(97)00766-1

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✦ Synopsis

The aldol reactions of ct-diazo-13-ketoesters with a variety of aldehydes produced adducts which underwent Rh(II)-catalyzed O-H insertion reaction to yield highly substituted tetrahydrofurans. Alkylation and decarboxylation of these tetrahydrofurans formed a wide

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