We report here a simple transformation of saturated car-bony1 derivatives 1 to cy, IJ--
Aldehydes and ketones from thioacetals
β Scribed by Fetizon, Marcel; Jurion, Michel
- Book ID
- 111860797
- Publisher
- The Royal Society of Chemistry
- Year
- 1972
- Tongue
- English
- Weight
- 116 KB
- Volume
- 7
- Category
- Article
- ISSN
- 0022-4936
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A recent report' on the preparation of aldehydes 2 from mercaptal S-oxides 'J ---via alkylation 3 of the carbanion of 2~' ---prompts us to communicate some pertinent data and views gained from our studies on disulfoxides and related compounds3. We have observed that disulfoxides 1 ---in CHC13 upon
Full exploitation of I70-NMR spectroscopy ['] in mechanistic organic chemistry requires efficient, simple methods for the synthesis of I70-labeled compounds. The classical method for labeling aldehydes and ketones with 1 7 0 or I8O is based on their reversible hydration['l. However, to obtain by thi