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Aldehydes and ketones from mercaptals via oxidation

✍ Scribed by H. Nieuwenhuyse; R. Louw

Book ID
104248352
Publisher
Elsevier Science
Year
1971
Tongue
French
Weight
104 KB
Volume
12
Category
Article
ISSN
0040-4039

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✦ Synopsis

A recent report' on the preparation of aldehydes 2 from mercaptal S-oxides 'J ---via alkylation 3 of the carbanion of 2~' ---prompts us to communicate some pertinent data and views gained from our studies on disulfoxides and related compounds3.

We have observed that disulfoxides 1 ---in CHC13 upon treatment with HCl gas at 0 -20Β°C ---are rapidly converted into their carbonyl analogues 2 plus CH3SSCH3 and CH3S02SCH3. As chlorine is formed as an intermediate, the first step --involving oxidation of HCl ---is the conversion of 2 '"to 1 4

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