Magnesium-oppenauer oxidation of alcohols to aldehydes and ketones
β Scribed by Brian Byrne; Michael Karras
- Publisher
- Elsevier Science
- Year
- 1987
- Tongue
- French
- Weight
- 185 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0040-4039
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β¦ Synopsis
Using a magnesium-Oppenauer oxidation aldehydes and ketones are prepared from halomagnesium alkoxides, which in turn are the products of Grignard reactions.
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## Abstract A (hydroxycyclopentadienyl)iron dicarbonyl hydride catalyzes the Oppenauerβtype oxidation of alcohols with acetone as the hydrogen acceptor. Many functional groups are tolerant to the oxidation conditions. The same complex also catalyzes the dehydrogenation of diols to lactones. A mecha
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