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Alcohols Oxidation with Hydrogen Peroxide Promoted by TPAP-Doped Ormosils.

✍ Scribed by Sandro Campestrini; Massimo Carraro; Rosaria Ciriminna; Mario Pagliaro; Umberto Tonellato

Book ID
101968739
Publisher
John Wiley and Sons
Year
2005
Weight
114 KB
Volume
36
Category
Article
ISSN
0931-7597

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New recyclable catalysts for aerobic alc
New recyclable catalysts for aerobic alcohols oxidation: sol-gel ormosils doped with TPAP
✍ Mario Pagliaro; Rosaria Ciriminna πŸ“‚ Article πŸ“… 2001 πŸ› Elsevier Science 🌐 French βš– 73 KB

Novel nanoporous materials have been prepared that are recyclable catalysts for the aerobic oxidation of activated and non-activated alcohols. The catalysts are organically modified silicas (ormosils) doped with tetra-n-propylammonium perruthenate (TPAP) via the sol-gel process. Hydrophobicity and f

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✍ Sandro Campestrini; Massimo Carraro; Rosaria Ciriminna; Mario Pagliaro; Umberto πŸ“‚ Article πŸ“… 2005 πŸ› John Wiley and Sons 🌐 English βš– 198 KB πŸ‘ 1 views

## Abstract The heterogeneous oxidation of various alcohols with oxygen catalysed by TPAP‐doped ormosils in scCO~2~ at 75 °C and 22.0β€…MPa has been studied in detail. Sol‐gel segregation of TPAP into the inner porosity of an organically modified silica (ormosil) xerogel along with the use of a react