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New recyclable catalysts for aerobic alcohols oxidation: sol-gel ormosils doped with TPAP

✍ Scribed by Mario Pagliaro; Rosaria Ciriminna


Publisher
Elsevier Science
Year
2001
Tongue
French
Weight
73 KB
Volume
42
Category
Article
ISSN
0040-4039

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✦ Synopsis


Novel nanoporous materials have been prepared that are recyclable catalysts for the aerobic oxidation of activated and non-activated alcohols. The catalysts are organically modified silicas (ormosils) doped with tetra-n-propylammonium perruthenate (TPAP) via the sol-gel process. Hydrophobicity and flexibility of the sol-gel cages were crucial in promoting catalysis.


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