Ag(I) Complexes of Some ω′-Aminoalkylpyridinium Compounds
✍ Scribed by L. C. van Poucke; H. F. De Brabander; Z. Eeckhaut
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 2010
- Weight
- 160 KB
- Volume
- 78
- Category
- Article
- ISSN
- 0037-9646
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The acidity constants of thew-aminocarboxylic acids with n = 1,2, 3. 4, 5 and the stability constants of the Ag(1) complexes of the corresponding aminocarboxylates were determined at O", 15" and 40°C in 0.5 M K N 0 3 . From thisand the samedata at 25", reported previously, the free energy, enthalpy
## Abstract Solid‐state cross‐polarization magic‐angle spinning (CP/MAS) NMR spectra were recorded for the compounds [Ag(NH~3~)~2~]~2~SO~4~, [Ag(NH~3~)~2~]~2~SeO~4~ and [Ag(NH~3~)~2~]NO~3~, all of which contain the linear or nearly linear two‐coordinate [Ag(NH~3~)~2~]^+^ ion. The ^109^Ag CP/MAS NMR