Aggregation: Models of the sol – gel transition
✍ Scribed by Hentschel, George
- Book ID
- 109739438
- Publisher
- Nature Publishing Group
- Year
- 1985
- Tongue
- English
- Weight
- 160 KB
- Volume
- 315
- Category
- Article
- ISSN
- 0028-0836
- DOI
- 10.1038/315719a0
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We present experimental results obtained near the sol-gel transition of polyurethane copolymer clusters in which the chemical reaction is a polycondensation reaction. The exponent r characteristic of the mass distribution and the exponent y characteristic of the growth process of polymer clusters as
## Abstract The gelation mechanism of aqueous solutions of methylcellulose (MC) with different molecular weights was studied by small deformation oscillation rheological measurments and differential scanning calorimetry (DSC). The gelation is promoted by the increase in molecular weight of MC: the