Aerobic Lactonization of Diols by Biomimetic Oxidation
✍ Scribed by Dr. Yoshinori Endo; Prof. Dr. Jan-E. Bäckvall
- Publisher
- John Wiley and Sons
- Year
- 2011
- Tongue
- English
- Weight
- 584 KB
- Volume
- 17
- Category
- Article
- ISSN
- 0947-6539
No coin nor oath required. For personal study only.
✦ Synopsis
Figure 1. Lowering the barriers for electron transfer by the use of ETMs. Scheme 1. Two step oxidation in metal-catalyzed lactonization.
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An Anderson-type polyoxometalate, [I VII Mo 6 O 24 ] 5± , has been used as a catalyst for the aerobic oxidation at 80 8C of vicinal diols (glycols). This is the first report on the use of such a polyoxometalate as an oxidation catalyst. Reactivity and selectivity were dependent on the substrate. Thu