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Aerobic Oxidation of Vicinal Diols Catalyzed by an Anderson-Type Polyoxometalate, [IMo6O24]5-.

✍ Scribed by Alexander M. Khenkin; Ronny Neumann


Publisher
John Wiley and Sons
Year
2003
Weight
170 KB
Volume
34
Category
Article
ISSN
0931-7597

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Aerobic Oxidation of Vicinal Diols Catal
✍ Alexanderβ€…M. Khenkin; Ronny Neumann πŸ“‚ Article πŸ“… 2002 πŸ› John Wiley and Sons 🌐 English βš– 85 KB πŸ‘ 1 views

An Anderson-type polyoxometalate, [I VII Mo 6 O 24 ] 5Β± , has been used as a catalyst for the aerobic oxidation at 80 8C of vicinal diols (glycols). This is the first report on the use of such a polyoxometalate as an oxidation catalyst. Reactivity and selectivity were dependent on the substrate. Thu