Efficient Ruthenium-Catalyzed Aerobic Oxidation of Amines by Using a Biomimetic Coupled Catalytic System
✍ Scribed by Joseph S. M. Samec; Alida H. Éll; Jan-E. Bäckvall
- Publisher
- John Wiley and Sons
- Year
- 2005
- Tongue
- English
- Weight
- 169 KB
- Volume
- 11
- Category
- Article
- ISSN
- 0947-6539
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## Abstract Environmentally friendly oxidation of primary aliphatic amines to imines has been successfully achieved, under metal‐free conditions, by the use of diverse electrogenerated __o__‐azaquinone mediators. High catalytic performance, together with high chemoselectivity, were observed with el
The oxidation of allylic and benzylic alcohols to aldehydes oxygen, in the presence of the bifunctional rutheniumcopper system (nPr 4 N)(RuO 4 )-CuCl acting as the catalyst. can be carried out at room temperature with molecular The oxidation of alcohols to aldehydes and ketones is a species [RuCl 2