Ultraviofet photoekction spectra from Rh~(C0)16 and from CO adsorbed on a Pd(l11) single crystal surfzce evhtblt cIose slmllarities which become further evident from a comparison of vibrational and thermal properties. These results demonstrate the localized character of the chemisorption bond and ju
Adsorption of CO and N2 on modified transition-metal surfaces
✍ Scribed by C.N.R. Rao; G.Ranga Rao
- Publisher
- Elsevier Science
- Year
- 1988
- Tongue
- English
- Weight
- 335 KB
- Volume
- 146
- Category
- Article
- ISSN
- 0009-2614
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✦ Synopsis
Electron spectroscopic studies clearly demonstrate that modification of the surfaces of Mn, Fe and Ni metals by chlorine significantly decreases the strength of interaction between the metal and adsorbed molecules such as CO and N2. This is in contrast to the effect of electropositive additives such as Ba and Al which increase the adsorption bond strength significantly.
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