Adsorption in polarographic reversible electrode reactions
✍ Scribed by M. Heyrovský; S. Vavřička; R. Heyrovská
- Book ID
- 104149357
- Publisher
- Elsevier Science
- Year
- 1973
- Weight
- 466 KB
- Volume
- 46
- Category
- Article
- ISSN
- 0022-0728
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Adsorption of reactants is a common complication in electrode reactions. Unfortunately, theoretical consideration of adsorption becomes mathematically arduous when it is combined with diffusional mass transfer, especially in cases d.escribed by non-linear adsorption isotherms. Thus, exact results pe
## Polarographic behaviour of dibenzoyhuethane in aqueous ethanol (40 "/. v/v) has been studied at 25 f O.l"C as a function of pH using MCI buffer. Two well-defined waves are obtained in the pH range 2.2-5.0. While the first wave which corresponds to one-electron reduction process is irreversible