Determination of electrode reaction parameters by using polarographic catalytic currents
β Scribed by Hiroko Kaneko
- Publisher
- Elsevier Science
- Year
- 1984
- Weight
- 451 KB
- Volume
- 169
- Category
- Article
- ISSN
- 0022-0728
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## Abstract An oscilloscopic method for the rapid determination of the kinetic parameters of an electrode reaction, making use of sine wave current is proposed. The features of the method as compared with the cyclic current step method of __Wijnen__ and __Smit__ are discussed. It is shown that the
Kinetic parameters of the electrode reaction of the Zn&+/Zn(Hg) electrode have been determined at various concentrations of supporting electrolyte by the polarographic and the potentiostatic methods. The corrections for the effect of the electrical double layer have been made on these parameters. At