Additions and Corrections - Photochemistry of Bicyclo[3.2.0.]hept-3-en-2-oness
β Scribed by Cargill, Robert; Sears, A.; Boehm, Jeffrey; Willcott, M.
- Book ID
- 126480959
- Publisher
- American Chemical Society
- Year
- 1976
- Tongue
- English
- Weight
- 123 KB
- Volume
- 98
- Category
- Article
- ISSN
- 0002-7863
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
## Abstract The chemistry of the highly substituted cyclobutanone derivative 2, which is easily accessible from 1, is dominated by the steric hindrance caused by the substitutents: Reduction with hydride reagents and nucleophilic additions with methyllithium are less stereoselective than correspond
Single crystal X-ray diffraction analysis of compounds A, B and, C helped us to assign the absolute configurations of the enantiomers of the bicyclo[3.2.0]hept-3-en-6-endo-ols 4-6. These bicyclic alcohols were easily obtained by: (i) stereoselective reductions of the bicyclo[3.2.0]hept-3-en-6-ones 1