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Photochemistry of bicyclo[3.2.0]hept-3-en-2-ones. Formation of 2-cyclohexenecarboxylic acid derivatives

✍ Scribed by Cargill, Robert L.; Sears, A. Bradford.


Book ID
126867979
Publisher
American Chemical Society
Year
1970
Tongue
English
Weight
222 KB
Volume
92
Category
Article
ISSN
0002-7863

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## Abstract The chemistry of the highly substituted cyclobutanone derivative 2, which is easily accessible from 1, is dominated by the steric hindrance caused by the substitutents: Reduction with hydride reagents and nucleophilic additions with methyllithium are less stereoselective than correspond