Previously identified, measured, and rotationally assigned but unpublished J Ο 0 -1 and 1-2 microwave a-dipole lines for excited states of the torsion for CH 2 DOH and CHD 2 OH are given torsional assignments for the first four excited states. The troublesome assignments were for the K Οͺ1 Ο 0 lines
Additional microwave torsional-rotational spectra of CH2DOH and CHD2OH, including excited torsional states
β Scribed by Chun Fu Su; Mujian Liu; C.Richard Quade
- Publisher
- Elsevier Science
- Year
- 1991
- Tongue
- English
- Weight
- 121 KB
- Volume
- 149
- Category
- Article
- ISSN
- 0022-2852
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π SIMILAR VOLUMES
Previous studies of the microwave rotational spectra of gauche CH 2 DCH 2 OH have been extended for the torsional ground state and new studies are reported for the first excited states of the -OH torsion. The extended studies for the ground state hydroxyl gauche, methyl symmetric conformation made i
The microwave spectroscopy of \(\mathrm{CH}_{2} \mathrm{DSH}\) and \(\mathrm{CHD}_{2} \mathrm{SH}\) has been revisited with the intent of identifying and assigning transitions in the excited torsional states. This effort has been successful, but in the course of the investigation it has been necessa
The microwave torsional-rotational spectra of gauche CH 3 CD 2 OH and CH 3 CD 2 OD have been identified, assigned, and analyzed up to 70 GHz. From the observed a-and c-dipole transitions, it has been possible to determine the effective rotational coefficients and the gauche tunneling energy of the h