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An internal axis approach for the internal rotation problem in asymmetric-asymmetric molecules: Application to the microwave torsional-rotational spectra of CH2DOH and CHD2OH

✍ Scribed by Mujian Liu; C.Richard Quade


Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
670 KB
Volume
146
Category
Article
ISSN
0022-2852

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Vibration–Internal Rotation–Overall Rota
✍ C.Richard Quade 📂 Article 📅 1999 🏛 Elsevier Science 🌐 English ⚖ 329 KB

The zeroth-order kinetic energy is developed for the vibrating-rotating-internally rotating CH(2)DOH and CHD(2)OH molecules using the general theory of Guan and Quade for the vibration-rotation-large amplitude internal motion interactions in molecules. A T transformation is applied to obtain the nec